VUV excitation properties of LnAl(3)B(4)O(12): Re (Ln = Y, Gd; Re=Eu, Tb)

Citation
Hp. You et al., VUV excitation properties of LnAl(3)B(4)O(12): Re (Ln = Y, Gd; Re=Eu, Tb), J PHYS CH S, 61(12), 2000, pp. 1985-1988
Citations number
20
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
ISSN journal
00223697 → ACNP
Volume
61
Issue
12
Year of publication
2000
Pages
1985 - 1988
Database
ISI
SICI code
0022-3697(200012)61:12<1985:VEPOLR>2.0.ZU;2-S
Abstract
Vacuum ultraviolet excitation spectra of LnAl(3)B(4)O(12):Re (Ln = Y, Gd; R e = Eu, To), along with X-ray photoelectron spectra, were measured. The spe ctra are tentatively interpreted in terms of the optical properties of the rare earth ions and the band structure. It was found that there is an energ y transfer from the hosts to the rare earth ions. It was also found that th e top of the valence band in the Gd compound is mainly formed by the 2p lev els of O2- and the 4f levels of Gd3+, and in the Y compound mainly by the 2 p levels of O2-. (C) 2000 Elsevier Science Ltd. All rights reserved.