W. Zhang et al., STUDY OF THE EFFECT OF THE SR CA RATIO ON THE MICROSTRUCTURE AND CRITICAL-CURRENT DENSITY OF BSCCO-2212 AG-SHEATHED TAPES/, IEEE transactions on applied superconductivity, 7(2), 1997, pp. 1544-1547
The effect of the Sr/Ca ratio and Bi content on the microstructure and
J(c) of Ag-sheathed 2212 tapes was studied, Changing the Sr/Ca ratio
changed the melting temperature of 2212 phase, the phase assemblage in
the melt, and the nonsuperconducting phases in the fully processed ta
pe, In tapes with Sr/Ca=2.75, the 2201 phase crystallizes from the mel
t before 2212 during cooling, and this 2201 remains in the microstruct
ure. In tapes with Sr/Ca=1.3, there is more liquid left after cooling,
and it converts to 2201 as the tape cools to room temperature, Fully
processed tape with overall composition 2.1:2:1:2 had the most homogen
eous microstructure and highest J(c).