A zwitterionic transition-metal complex: Platinum-closo-borate coordination synthesis, structure, and DFT calculations

Authors
Marx, T Wesemann, L Dehnen, S
Citation
T. Marx et al., A zwitterionic transition-metal complex: Platinum-closo-borate coordination synthesis, structure, and DFT calculations, ORGANOMETAL, 19(22), 2000, pp. 4653-4656
Citations number
42
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
19
Issue
22
Year of publication
2000
Pages
4653 - 4656
Database
ISI
SICI code
0276-7333(20001030)19:22<4653:AZTCPC>2.0.ZU;2-Q
Abstract
A zwitterionic platinum(IV) complex comprising a cationic transition-metal center and an anionic heteroborate cluster was synthesized and structurally characterized On. the basis of DFT calculations a dipole moment of 29.8 D was determined for this polar molecule.