The influence of dispersionless quantum optical phonons on the phase diagra
m of a quarter-filled Hubbard chain is studied using the density-matrix ren
ormalization group technique. The ground state phase diagram is obtained fo
r frequencies corresponding to the intramolecular vibrations in organic con
ductors. For high vibrational modes the system is only slightly affected by
the electron-phonons coupling. It remains in a Luttinger liquid phase as l
ong as the electronic repulsion is larger than the polaronic binding energy
. For low vibrational modes the phase diagram is very rich. A noticeable po
int is the existence of a 4k(F) charge-density wave phase for small values
of the correlation strength. For realistic values of the electron repulsion
and of the electron-phonons coupling constant a large phonons-mediated red
uction of the Luttinger liquid parameter K-rho was found compared to the pu
re electronic model.