G. Camino et al., Comparison of the roles of two shrinkage-control led low-profile additivesin water aging of polyester resin-glass fiber composites, POLYM COMP, 21(5), 2000, pp. 821-831
A model previously formulated or water sorption in polyester resin-glass fi
ber composites has been applied to the kinetic analysis of experimental dat
a for two composites containing a hydrolysable (polyvinyl acetate-PVAc) and
a non-hydrolyzable (polystyrene-PS) shrinkage-controlling low-profile addi
tive (LPA) respectively. It was found that the equilibrium water uptake in
the composites and their unreinforced matrix is not drastically affected by
the type of LPA. The kinetics of water sorption in the composites, however
, were substantially different. The PVAc composite displayed a two-stage so
rption process, the first stage being attributed to diffusion combined with
hydrolysis, and the second to matrix swelling and plasticizing. A maximum
in the kinetic curve was observed, and was due to changes in water solubili
ty inside the matrix during sorption. In contrast, the PS composite display
ed the typical kinetics of materials with slowly increasing hydrophilicity.