P. Costagliola et al., SR-ISOTOPE COMPOSITION OF BARITE VEINS AT POLLONE DEPOSIT, APUANE ALPS, TUSCANY (ITALY), Chemie der Erde, 57(2-3), 1997, pp. 231-242
The barite (+/- Pb, Zn, Ag) deposit of Pollone is hosted within a sili
ciclastic formation of pre-Norian age, belonging to the Apuane Alps (A
A) basement, metamorphosed during the Apenninic orogeny (P = 3-4 Kbar;
T = 350-450 degrees C). The deposit consist of both stratiform and ve
in orebodies. The former are of possible syngenetic origin, whereas th
e latter are ascribed to syn-metamorphic remobilization of pre-existin
g anomalies. In particular, a syn-metamorphic shear-zone, extensively
affecting the northern sector of the deposit, favored intense circulat
ion and focusing of fluids, leading to the emplacement of a number of
metamorphogenic barite +/- polymetallic sulfide orebodies. The geochem
ical features of stratiform and vein orebodies and of their host rocks
have been used to constrain the hydrology and possible provenance of
mineralizing fluids. Syngenetic barites are systematically Sr-87-deple
ted with respect to epigenetic barites, indicating that they did not a
ct as a Sr-isotope buffer for syn-metamorphic mineralizing fluids. In
addition, the Sr-isotope composition of host rocks does not reflect eq
uilibrium with adjoining vein bodies. These results indicate that (1)
interaction between mineralizing fluids, syngenetic barite and host ro
cks was rather scarce, reflecting a channeled rather than pervasive fl
uid flow; (2) the source of radiogenic Sr was not represented by Pollo
ne host rocks, but possibly by basement rocks located at depth below t
he barite orebodies. This conclusion is in accordance with previous da
ta on Rb and Sr geochemistry.