SYNTHESIS OF NEW AMIDO, ALKOXO AND ETA-CYCLOPENTADIENYL DERIVATIVES OF MOLYBDENUM

Citation
Xf. Yan et al., SYNTHESIS OF NEW AMIDO, ALKOXO AND ETA-CYCLOPENTADIENYL DERIVATIVES OF MOLYBDENUM, Journal of the Chemical Society. Dalton transactions, (12), 1997, pp. 2091-2099
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
03009246
Issue
12
Year of publication
1997
Pages
2091 - 2099
Database
ISI
SICI code
0300-9246(1997):12<2091:SONAAA>2.0.ZU;2-B
Abstract
The new compounds [Mo(eta-Me3SiC5H4)(NMe2)(3)], [Mo(eta-Me3SiC5H4)(2)H -2], [Mo(eta-C9H7)(NMe2)(3)] [Mo(eta-C5H5)-(S2CNMe2)(3)], [Mo(eta-C5H5 )(OPr1)(NMe2)(2)], [Mo(eta-C5H5)(OPr1)(2)(NMe2)], [Mo(eta-C5H5)(OBut)( NMe2)(2)], [Mo(eta-C5H5)(OBut)(2)(NMe2)], [Mo(eta-C5H5)(OC6H2Me-4-Bu-2 (t)-2,6) (NMe2)(2)], [Mo(eta-C5H5)(OC6H3Me-6-Bu-t-2)(NMe2)(2)], [Mo(et a-C5H5)(OC5H4But-p)(NMe2)(2)], [Mo(OR)(4)(HNMe2)(2)] (R=p-MeC6H4 or p -(BuC6H4)-C-t) and [Mo(OC6H4Me-p),(NMe2)(2)] have been prepared and c haracterised. The asterisk indicates the crystal structure 1 has been determined.