Convenient method for the reduction of the double-bond of cyclic vinylphosphine oxides using borane

Authors
Keglevich, G Fekete, M Chuluunbaatar, T Dobo, A Bocskei, Z Toke, L
Citation
G. Keglevich et al., Convenient method for the reduction of the double-bond of cyclic vinylphosphine oxides using borane, SYN COMMUN, 30(23), 2000, pp. 4221-4231
Citations number
12
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
30
Issue
23
Year of publication
2000
Pages
4221 - 4231
Database
ISI
SICI code
0039-7911(2000)30:23<4221:CMFTRO>2.0.ZU;2-A
Abstract
The electronpoor double-bond of cyclic vinylphosphine oxides (1, 3 and 4) i s easily reduced by borane in a selective manner to give the corresponding saturated derivatives (2, 4 and 5, respectively) Under forcing conditions, change of the functionality may also take place.