Asymmetric synthesis of 1-alkynylcyclopropane-1-carboxylates

Authors
Davies, HML Boebel, TA
Citation
Hml. Davies et Ta. Boebel, Asymmetric synthesis of 1-alkynylcyclopropane-1-carboxylates, TETRAHEDR L, 41(43), 2000, pp. 8189-8192
Citations number
15
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
43
Year of publication
2000
Pages
8189 - 8192
Database
ISI
SICI code
0040-4039(20001021)41:43<8189:ASO1>2.0.ZU;2-1
Abstract
Dirhodium tetrakis(S-(N-dodecylbenzenesulfonyl)prolinate)(Rh2S-DOSP4) catal yzed decomposition of methyl alkynyldiazoacetates in the presence of alkene s results in highly diastereoselective and enantioselective cyclopropanatio ns. (C) 2000 Published by Elsevier Science Ltd.