New proton-ionizable, cesium-selective calix[4]arene-bis(crown-6-ethers) with markedly enhanced extraction efficiency

Citation
Vs. Talanov et al., New proton-ionizable, cesium-selective calix[4]arene-bis(crown-6-ethers) with markedly enhanced extraction efficiency, TETRAHEDR L, 41(43), 2000, pp. 8221-8224
Citations number
13
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
43
Year of publication
2000
Pages
8221 - 8224
Database
ISI
SICI code
0040-4039(20001021)41:43<8221:NPCCW>2.0.ZU;2-I
Abstract
The first 1,3-alternate calix[4]arene-bis(crown-6-ethers) with a proton-ion izable group located in front of one crown ether cavity are synthesized. Co mpared with an analog that has no proton-ionizable group, the two new ligan ds possess markedly higher Cs+ extraction efficiency. (C) 2000 Elsevier Sci ence Ltd. All rights reserved.