A novel, reversible, water-swellable chitin gel has been produced by t
he carboxymethylation of a dry chitin film. The property of this mater
ial is that unlike carboxymethyl-chitin, it takes up water but is not
soluble and retains a degree of rigidity even when wet. The degree of
swelling depends on the reaction conditions and alkali (sodium or pota
ssium hydroxide) used as a co-reactant during the carboxymethylation.
Upon drying, the gel returns to its dry film form. This water uptake a
nd loss is cyclic, which is a desirable property in certain applicatio
ns and is a tremendous advantage in the handling of this material. (C)
1997 John Wiley & Sons, Inc.