Highly selective reaction of propargyl bromide with carbonyl compounds promoted by metal dysprosium

Authors
Li, ZM Jia, Y Zhou, JY
Citation
Zm. Li et al., Highly selective reaction of propargyl bromide with carbonyl compounds promoted by metal dysprosium, ACT CHIM S, 58(10), 2000, pp. 1301-1306
Citations number
23
Categorie Soggetti
Chemistry
Journal title
ACTA CHIMICA SINICA
ISSN journal
05677351 → ACNP
Volume
58
Issue
10
Year of publication
2000
Pages
1301 - 1306
Database
ISI
SICI code
0567-7351(2000)58:10<1301:HSROPB>2.0.ZU;2-N
Abstract
Promoted by metal dysprosium, aldehydes and ketones could react smoothly wi th propargyl bromide to afford the corresponding homopropargylic alcohols i n good to excellent yields, and no allenic alcohols were found. However, ca rbonyl compounds only afford the corresponding allenic alcohols when propar gyl bromide was replaced by 1-phenyl-3-bromopropargyl bromide,and no homopa rgylic alcohols were formed.