Reduction of conjugate double bonds with trichlorosilane

Citation
M. Chauhan et P. Boudjouk, Reduction of conjugate double bonds with trichlorosilane, CAN J CHEM, 78(11), 2000, pp. 1396-1398
Citations number
17
Categorie Soggetti
Chemistry
Journal title
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
ISSN journal
00084042 → ACNP
Volume
78
Issue
11
Year of publication
2000
Pages
1396 - 1398
Database
ISI
SICI code
0008-4042(200011)78:11<1396:ROCDBW>2.0.ZU;2-B
Abstract
A variety of alpha,beta -unsaturated esters and cyclic ketones underwent sm ooth reduction of the carbon-carbon double bond with a combination of inexp ensive and readily available trichlorosilane and CoCl2. The reactions are p erformed under very mild conditions and products are obtained in high yield s.