Stereo- and regiospecific polymerization of cyclic conjugated dienes usinghighly active nickel catalysts

Authors
Nakano, M Yao, Q Usuki, A Tanimura, S Matsuoka, T
Citation
M. Nakano et al., Stereo- and regiospecific polymerization of cyclic conjugated dienes usinghighly active nickel catalysts, CHEM COMMUN, (22), 2000, pp. 2207-2208
Citations number
11
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
22
Year of publication
2000
Pages
2207 - 2208
Database
ISI
SICI code
1359-7345(2000):22<2207:SARPOC>2.0.ZU;2-V
Abstract
A markedly active and selective nickel catalyst, bis(allylnickel bromide)-m ethylaluminoxane, has been developed for cyclohexa-1,3-diene polymerization ; the obtained crystalline polymer is a 1,4-linked cis-syndiotactic structu re as determined by NMR and molecular dynamics using the COMPASS force fiel d.