Intercalation of spirooxazine induced by zinc cation chelation in montmorillonite and its photochromic behavior

Citation
H. Nishikiori et al., Intercalation of spirooxazine induced by zinc cation chelation in montmorillonite and its photochromic behavior, CHEM LETT, (10), 2000, pp. 1142-1143
Citations number
16
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
10
Year of publication
2000
Pages
1142 - 1143
Database
ISI
SICI code
0366-7022(20001005):10<1142:IOSIBZ>2.0.ZU;2-9
Abstract
Spirooxazine (SPO) was introduced into hydrophobically modified montmorillo nite dispersed in acetone under UV illumination in the presence of zinc ion s. The fluorescence spectra of the samples exhibited photochromic behavior arising from the photoinduced interconversion between the original species of SPO and the Zn-chelated complex of the SPO-derived merocyanine.