Surface organometallic chemistry of tin: Grafting reaction of Sn(CH3)(4) in HY zeolite supercage

Authors
Wang, XX Zhao, HX Lefebvre, F Basset, JM
Citation
Xx. Wang et al., Surface organometallic chemistry of tin: Grafting reaction of Sn(CH3)(4) in HY zeolite supercage, CHEM LETT, (10), 2000, pp. 1164-1165
Citations number
8
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
10
Year of publication
2000
Pages
1164 - 1165
Database
ISI
SICI code
0366-7022(20001005):10<1164:SOCOTG>2.0.ZU;2-S
Abstract
Tetramethyltin reacts rapidly, even at low temperature, with the hydroxy gr oups in the supercages of HY zeolite, resulting in the formation of well-de fined -Sn(CH3)(3) fragments in the supercages. This reaction is very select ive as there is no reaction with the hydroxy groups in the sodalite cages a nd prisms.