A simple synthesis and the crystal structure of a novel tetranuclear diorganotin compound

Authors
Dey, DK Saha, MK Mitra, S Bansal, RK Dahlenburg, L
Citation
Dk. Dey et al., A simple synthesis and the crystal structure of a novel tetranuclear diorganotin compound, CHEM LETT, (10), 2000, pp. 1190-1191
Citations number
12
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
10
Year of publication
2000
Pages
1190 - 1191
Database
ISI
SICI code
0366-7022(20001005):10<1190:ASSATC>2.0.ZU;2-U
Abstract
The tetranuclear dimethyltin(IV) complex (L)SnMe2(mu O-3)(SnMe2)(2)(mu (3)- O)SnCl2Me2, which was obtained from Me2SnCl2 and the tetradentate Schiff ba se ligand N-2-[3'-(methoxysalicylideneimino)benzyl]-3 "- -methoxysalicylide neimine (H2L) avoiding strictly moisture-free conditions, displays one seve n and three five-coordinate dimethyltin moieties bridged by two mu (3)-oxo groups as the basic structural features. Retention of solid state structure in solution is indicated by NMR spectra.