A novel hydrogen-bonded duplex made up of water molecules and halide ions in the sandwich inclusion structures of (C10H8N3S)(+)center dot X center dot 2H(2)O [X=Cl-,Br-] (Sept, pg 1080, 2000)

Citation
P. Prabakaran et al., A novel hydrogen-bonded duplex made up of water molecules and halide ions in the sandwich inclusion structures of (C10H8N3S)(+)center dot X center dot 2H(2)O [X=Cl-,Br-] (Sept, pg 1080, 2000), CHEM LETT, (10), 2000, pp. 1229
Citations number
12
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
10
Year of publication
2000
Database
ISI
SICI code
0366-7022(20001005):10<1229:ANHDMU>2.0.ZU;2-B
Abstract
The X-ray crystal structures of thiabendazolium halide dihydrates (C10H8N3S )(+).X . 2H(2)O [X = Cl-, Br-] 1, 2 reveal a novel hydrogen-bonded duplex c onsisting of alternate edge-sharing (H2O .X)(2) quadrilaterals and (2H(2)O .X)(2) hexagons; notably these duplexes exist as host lattices and sandwich thiabendazole molecules into two different supramolecular architectures by similar N . . .X and N . . .O hydrogen bonds.