A modified Bragg law for straightforward determining the film thickness by
low-angle X-ray reflection was derived based on the geometrical optical the
ory. We showed that this modified Bragg law and its inference formulae coul
d be used to accurately determine the thickness of the monolayer or multila
yer film. Furthermore, the modified Bragg law for determining the superlatt
ice period presented earlier by others can be derived from the above modifi
ed Bragg law. The similar inference formulae were also given. The precision
in determining the film thickness and/or superlattice period by the above
formulae was discussed.