The behaviour of fine particles in the flotation separation of mineral
s has become of rapidly increasing importance as new, fine grained dep
osits are exploited. Fine particles float poorly and less-selectively
under normal flotation conditions. The behaviour of fine (<20 mu m) an
d coarse (38-75 mu m) sphalerite has been correlated between microflot
ation and aggregation studies. This study utilises two novel technique
s for obtaining direct evidence of particle interactions within a cond
itioning pulp. On-line particle size distribution enables the onset of
aggregation of fine particles under potation related conditions, duri
ng addition of reagents, to be determined Concurrent evidence of parti
cle interactions has been observed using optical microscopy. Significa
nt aggregation to 20-30 mu m aggregates during agitation conditioning
before reagents was observed. Fine particles exhibit poor flotation re
sponse and some aggregation after Cu(II) activation alone. On addition
of collector at tow pH, potation recovery and extent of aggregation (
>100 mu m) increased dramatically. In the presence of coarse particles
at low pH, a high percentage of fine particles were recovered indicat
ing a fine-coarse particle aggregation (''piggy-backing'') mechanism o
ccurring during conditioning with Cu(II) alone. (C) 1997 Elsevier Scie
nce Ltd.