Citation
Vp. Fedin et al., A three-dimensional, cyano-bridged cluster-metal coordination compound with large cavities, EUR J INORG, (11), 2000, pp. 2341-2343
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948
→ ACNP
Issue
11
Year of publication
2000
Pages
2341 - 2343
Database
ISI
SICI code
1434-1948(200011):11<2341:ATCCCC>2.0.ZU;2-0
Abstract
By very slow diffusion of aqueous solutions of CoCl2. 6H(2)O and K-6[W4Te4(
CN)(12)]. 5H(2)O through silica gel, single crystals Of [Co(H2(O))(4)](3)[W
4Te4(CN)(12)]. 15.38H(2)O were obtained. A complete X-ray structure determi
nation reveals an extremely porous, three-dimensional neutral cluster-expan
ded framework structure with large water-filled cuboidal cavities.