Synthesis of galactofuranosides by regioselective ring opening of a 1,4-anhydrogalactopyranose derivative: A possible chemical model for an unprecedented enzymatic reaction
J. Kovensky et P. Sinay, Synthesis of galactofuranosides by regioselective ring opening of a 1,4-anhydrogalactopyranose derivative: A possible chemical model for an unprecedented enzymatic reaction, EUR J ORG C, (21), 2000, pp. 3523-3525
The known 1,4-anhydro-2,3,6-tri-O-benzyl-beta -D-galactopyranose(1) has bee
n regioselectively ring-opened using a variety of nucleophiles under acidic
conditions to exclusively afford furanosides.