Phase equilibrium calculations for semicontinuous mixtures subject to gravitational fields

Citation
Ro. Esposito et al., Phase equilibrium calculations for semicontinuous mixtures subject to gravitational fields, IND ENG RES, 39(11), 2000, pp. 4415-4421
Citations number
27
Categorie Soggetti
Chemical Engineering
Journal title
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN journal
08885885 → ACNP
Volume
39
Issue
11
Year of publication
2000
Pages
4415 - 4421
Database
ISI
SICI code
0888-5885(200011)39:11<4415:PECFSM>2.0.ZU;2-I
Abstract
A recently proposed algorithm for performing thermodynamic equilibrium calc ulations subject to the influence of the gravitational field is extended to semicontinuous mixtures. The characterization of the continuous families i s done by a pseudocomponent discretization based on a convenient choice of orthogonal polynomials to sample the distribution function interval. Then, adequate quadrature points and weights are calculated. We present results f or a family of hydrocarbons from C-8 to C-20 with 51 mol % of methane for o ne-phase, two-phase, three-phase, and near-critical systems. Our results sh ow the validity of the procedure for simulations of deep reservoirs and hig h-pressure storage conditions, solving problems with a high number of indep endent variables.