Preparation of 2,5-iminoazepines via the imine-ene reaction of 3-allylamino-2-(substituted)acrolein imines

Authors
Takamura, S Yamada, H Michinaka, T Yamamoto, H Kakehi, A Noguchi, M
Citation
S. Takamura et al., Preparation of 2,5-iminoazepines via the imine-ene reaction of 3-allylamino-2-(substituted)acrolein imines, J CHEM R-S, (9), 2000, pp. 426-428
Citations number
8
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF CHEMICAL RESEARCH-S
ISSN journal
03082342 → ACNP
Issue
9
Year of publication
2000
Pages
426 - 428
Database
ISI
SICI code
0308-2342(200009):9<426:PO2VTI>2.0.ZU;2-D
Abstract
Malonaldehyde derivatives 1 and 2 with an excess of allylamine (3a) in refl uxing toluene gave 2,5-iminoazepines 6a and 9a in moderate yields via the t hermal imine-ene reaction of the initially formed vinamidines 5a and 8a.