Primary acoustic thermometry between T=90 K and T=300 K

Citation
Mb. Ewing et Jpm. Trusler, Primary acoustic thermometry between T=90 K and T=300 K, J CHEM THER, 32(9), 2000, pp. 1229-1255
Citations number
33
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL THERMODYNAMICS
ISSN journal
00219614 → ACNP
Volume
32
Issue
9
Year of publication
2000
Pages
1229 - 1255
Database
ISI
SICI code
0021-9614(200009)32:9<1229:PATBTK>2.0.ZU;2-Z
Abstract
Differences between thermodynamic temperature and temperatures on the Inter national Temperature Scale of 1990 (ITS-90) have been measured at seven tem peratures between T = 90 K and T = 300 K using a primary acoustic thermomet er. The thermometer, which is based on a spherical acoustic resonator, yiel ds values of the quantity u/a, where u is the speed of sound in the thermom etric fluid (argon) and a is the radius of the resonator. Values of u/a in a single sample of argon were obtained at each of the temperatures, except the lowest, and at the temperature of the triple point of water (T-t) from pseudo-isochoric measurements. The results were combined with measurements of u/a along isotherms to obtain highly precise estimates of the quantity A (0)/a(2) at each temperature, where A(0) is the value of u(2) in the limit of zero density. At the lowest temperature, a simplified procedure was adop ted in which A(0)/a(2) was determined directly from an isotherm. Since a mo natomic gas was used, the values of A(0)(T) are proportional to the thermod ynamic temperature T. Finally, the values A(0)/a(2) were combined with micr owave measurements of the thermal expansion of the spherical resonator to o btain the ratios A(0)(T)/A(0)(T-t) from which thermodynamic temperatures we re evaluated. The results, which have an estimated standard uncertainty of between 0.9 mK and 1.3 mK, deviate significantly from ITS-90. (C) 2000 Acad emic Press.