A. Campargue et al., The absorption spectrum of HDO in the 16 300-16 670 and 18 000-18 350 cm(-1) spectral regions, J MOL SPECT, 204(1), 2000, pp. 94-105
The absorption spectrum of HDO has been recorded by Intracavity Laser Absor
ption Spectroscopy in the 16 300-16 670 and 18 000-18 350 cm(-1) spectral r
egions corresponding to the weak 2v(2) + 4v(3) and v(2) + 5v(3) bonds, resp
ectively. The v(2) + 5v(3) band centered at 18 208.434 cm(-1) was found alm
ost isolated and has been satisfactorily reproduced in the frame of the eff
ective Hamiltonian model. On the other hand, the 2v(2) + 4v(3) band at 16 4
56.201 cm(-1) is strongly perturbed as the (0 2 4) bright state is involved
in a complex interaction scheme including the (1 0 4), (5 0 1), (1 5 2), a
nd (1 11 0) states. The rovibrational assignment of these interacting state
s was greatly helped by the high-accuracy ab initio predictions performed b
y D. Schwenke and H. Partridge [J. Chem. Phys. 000-000 (2000)]. They could
be partly modeled by an effective Hamiltonian which has allowed the assignm
ent and reproduction of most of the observed transitions. (C) 2000 Academic
Press.