The essential function of carotenoids in photosynthesis is to act as photop
rotective agents, preventing chlorophylls and bacteriochlorophylls from sen
sitizing harmful photodestructive reactions in the presence of oxygen. Base
d upon recent structural studies on reaction centres and antenna complexes
from purple photosynthetic bacteria, the detailed organization of the carot
enoids is described. Then with specific reference to bacterial antenna comp
lexes the details of the photoprotective role, triplet-triplet energy trans
fer, are presented.