Electrical properties of structures consisting of CaF2 and Si nanosize laye
rs have been investigated. Then is a strong asymmetry between forward and r
everse current curves, as well as a shift of the voltage at which the curre
nt is null. It has been found that after some electrical forming of the str
uctures the current exhibits a well resolved non-monotonous N-type behavior
at reverse bias conditions. The corresponding region of negative different
ial resistance appears only once a forward bias has been applied. An attemp
t is made to interpret the observed effect in terms of capturing of the car
riers within the structure and their subsequent release through the structu
re via tunneling.