Quantum diffusion and catalyzed conversion of ortho-H-2 molecules in solidhydrogen

Citation
V. Shevtsov et al., Quantum diffusion and catalyzed conversion of ortho-H-2 molecules in solidhydrogen, PHYS REV B, 62(18), 2000, pp. 12386-12394
Citations number
24
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
PHYSICAL REVIEW B
ISSN journal
01631829 → ACNP
Volume
62
Issue
18
Year of publication
2000
Pages
12386 - 12394
Database
ISI
SICI code
0163-1829(20001101)62:18<12386:QDACCO>2.0.ZU;2-G
Abstract
The ortho-para conversion in solid hydrogen catalyzed by a small amount (si milar to 10(-3)) of OZ impurities was studied to determine the temperature and concentration dependence of the ortho-H-2 diffusion coefficient. For T> 5 K the diffusion coefficient has the activation-type dependence on tempera ture D(T) = 2 x 10(-11) exp(-92/T) cm(2) s(-1) and is independent of the or tho-Hz concentration C. For T<4 K this coefficient substantially changes it s behavior and far C in the range 0.02-0.75 it can be described by the rela tion D(T,C) = 1 x 10(-21). T/C cm(2) s(-1). The results obtained are interp reted in terms of the quantum diffusion of ortho-H-2 molecules in sold hydr ogen.