ANOMALOUS BEHAVIOR OF SOUND-VELOCITY AND ATTENUATION IN LIQUID FE-NI-S

Citation
Pm. Nasch et al., ANOMALOUS BEHAVIOR OF SOUND-VELOCITY AND ATTENUATION IN LIQUID FE-NI-S, Science, 277(5323), 1997, pp. 219-221
Citations number
52
Categorie Soggetti
Multidisciplinary Sciences
Journal title
ISSN journal
00368075
Volume
277
Issue
5323
Year of publication
1997
Pages
219 - 221
Database
ISI
SICI code
0036-8075(1997)277:5323<219:ABOSAA>2.0.ZU;2-1
Abstract
The compressional wave velocity in molten iron containing 5 percent ni ckel and 10 percent sulfur increased with increasing temperature. This anomalous behavior was determined to be attributable to-the presence of sulfur, which conditions the formation of large molecular units in the liquid. Temperature-induced breakup of macromolecular units result ed in greater packing efficiency and an increased velocity. Ten percen t sulfur increased attenuation by one to two orders of magnitude compa red with liquid iron, Such behavior at outer core pressures and temper atures would constrain the velocity gradient in the outer core and wou ld enable the discrimination of potential light alloying elements.