Performance degradation in CZ(B) cells and improved stability high efficiency PERT and PERL silicon cells on a variety of SEH MCZ(B), FZ(B) and CZ(Ga) substrates
Jh. Zhao et al., Performance degradation in CZ(B) cells and improved stability high efficiency PERT and PERL silicon cells on a variety of SEH MCZ(B), FZ(B) and CZ(Ga) substrates, PROG PHOTOV, 8(5), 2000, pp. 549-558
The cells made on CZ(B) (boron doped Czochralski) silicon substrates often
exhibit degraded minority carrier lifetimes corresponding to poorer cell pe
rformance. The first part of this paper reports our cell results on a varie
ty of CZ(B) substrates. Most of these CZ(B) cells showed a severely reduced
cell performance after being stored for a period of time. The cells on hig
her resistivity CZ(B) substrates from Crysteco Inc., showed no degradation
due to its low boron level of 10 Omega -cm resistivity.
The second part of this paper describes work avoiding this CZ(B) degradatio
n problem by using different substrate growth methods or different dopant,
such as MCZ(B) (boron doped magnetically confined Czochralski grown), CZ(Ga
) (gallium doped Czochralski), and FZ(B) (boron doped float zone) substrate
s. All these substrates were supplied by Shin-Etsu Handotai Co, Japan, (SEH
). High efficiency PERL (passivated emitter, rear locally-diffused) cell an
d Pert (passivated emitter, rear totally-diffused) cell structures were use
d for these cells. The best energy conversion efficiency of 24.5% has been
demonstrated by a PERT cell on a MCZ(B) substrate. This is the highest ener
gy conversion efficiency ever reported by a silicon cell made on a non-FZ s
ubstrate. All these cells have shown stable performances after a period of
storage. The PERT cell structure has also considerably reduced the cell ser
ies resistance from higher resistivity substrates. A total rear boron diffu
sion in this PERT structure also appears to improve the surface passivation
quality of MCZ(B) and some FZ(B) substrates. Hence, higher open-circuit vo
ltages were observed for these PERT cells. It is also believed that these M
CZ(B) and other SEH materials have considerably improved material qualities
under SEH's current effort to develop high quality substrates particularly
for photovoltaic applications. Copyright (C) 2000 John Wiley & Sons, Ltd.