Localized corrosion processes of passive metals are almost always initiated
at local heterogeneities of the substrate material. In the case of stainle
ss steels MnS inclusions are of primary importance. Increasing the temperat
ure strongly accelerates the pitting. Detailed large-scale and microelectro
chemical investigations show that this is mainly caused by an enhanced anod
ic dissolution facilitating stable pit growth and retarding repassivation.
Activation of new inclusions, remaining inactive at lower temperature, may
also occur but are of minor importance.