Lanthanide complexes with acetylacetonate and 5,10,15,20-tetra[4-(4-chlorobenzoyloxy)phenyl]porphyrin ligands

Authors
Xin, ZZ Wei, L Ming, J Fa, LG
Citation
Zz. Xin et al., Lanthanide complexes with acetylacetonate and 5,10,15,20-tetra[4-(4-chlorobenzoyloxy)phenyl]porphyrin ligands, SYN REAC IN, 30(9), 2000, pp. 1747-1758
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
ISSN journal
00945714 → ACNP
Volume
30
Issue
9
Year of publication
2000
Pages
1747 - 1758
Database
ISI
SICI code
0094-5714(2000)30:9<1747:LCWAA5>2.0.ZU;2-6
Abstract
Lanthanide complexes of acetylacetonate and 5,10,15,20-tetra[4-(4-chloroben zoyloxy)phenyl]porphyrin having the general formula Ln[(ClBOP)(4)P](acac) ( where Ln = Tb. Ho. Er, Tm; ClBOP = (4-chlorobenzoyloxy)phenyl: Hacac = acet ylacetone; P = porphyrin) have been prepared and characterized. A structure is proposed in which one 5,10,15,20-tetra[4-(4-chlorobenzoyloxy)phenyl]por phyrin is coordinated to a rare earth ion in a tetradentate fashion, while one acetylacetonate is coordinated to the same metal ion in a bidentate fas hion.