Gyroxanthin - the first allenic acetylenic carotenoid

Citation
T. Bjornland et al., Gyroxanthin - the first allenic acetylenic carotenoid, TETRAHEDRON, 56(46), 2000, pp. 9047-9056
Citations number
54
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
56
Issue
46
Year of publication
2000
Pages
9047 - 9056
Database
ISI
SICI code
0040-4020(20001110)56:46<9047:G-TFAA>2.0.ZU;2-3
Abstract
Selected recent studies on marine allenic and acetylenic carotenoids are fo cused on. The structure elucidation of gyroxanthin, (3S,5R,6S,3'S,5'R,6'R)- 5,6-epoxy-6,7,7',8'-tetradehydro-5',6'-tetrahydro-beta,beta -carotene-3,19, 3',5'-tetrol, is reported in detail and in historical perspective. Gyroxant hin occurs as a diester (19-dodecanoate 3'-acetate) in the dinoflagellate G ymnodinium galatheanum. (C) 2000 Elsevier Science Ltd. All rights reserved.