Synthesis and crystal structure of a stable S-nitrosothiol bearing a novelsteric protection group and of the corresponding S-nitrothiol

Authors
Goto, K Hino, Y Kawashima, T Kaminaga, M Yano, E Yamamoto, G Takagi, N Nagase, S
Citation
K. Goto et al., Synthesis and crystal structure of a stable S-nitrosothiol bearing a novelsteric protection group and of the corresponding S-nitrothiol, TETRAHEDR L, 41(44), 2000, pp. 8479-8483
Citations number
14
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
44
Year of publication
2000
Pages
8479 - 8483
Database
ISI
SICI code
0040-4039(20001028)41:44<8479:SACSOA>2.0.ZU;2-1
Abstract
The molecular structure of a stable S-nitrosothiol bearing a novel trityl-t ype steric protection group was established by X-ray crystallographic analy sis together with that of the corresponding S-nitrothiol. It was found that the S-nitrosothiol exists as a mixture of the syn and anti isomers with re spect to the C-S-N-O linkage in the crystalline state, in agreement with th e theoretical calculation on Ph3CSNO. (C) 2000 Elsevier Science Ltd. All ri ghts reserved.