Solution-free methods for the determination of the molecular-mass distribution of polymers

Authors
Citation
Vi. Irzhak, Solution-free methods for the determination of the molecular-mass distribution of polymers, USP KH, 69(8), 2000, pp. 780-788
Citations number
121
Categorie Soggetti
Chemistry
Journal title
USPEKHI KHIMII
ISSN journal
00421308 → ACNP
Volume
69
Issue
8
Year of publication
2000
Pages
780 - 788
Database
ISI
SICI code
0042-1308(2000)69:8<780:SMFTDO>2.0.ZU;2-P
Abstract
Methods for the estimation of the molecular-mass distribution of block poly mers known to date are considered. The methods are based on the analysis of the curve of the how of melts, the frequency dependence of the relaxation modules, the shape of the curve of the free induction decay (the method of pulse nuclear magnetic resonance) and the temperature dependence of complia nce in the region of high-elasticity plateau (thermomechanical analysis).