Three different functions of a phosphinic amidato ligand in LNi(LLi)(LH) {L = [(Bu2P)-Bu-t(O)NEt](-)}

Authors
Kuchen, W Wunderlich, H
Citation
W. Kuchen et H. Wunderlich, Three different functions of a phosphinic amidato ligand in LNi(LLi)(LH) {L = [(Bu2P)-Bu-t(O)NEt](-)}, ACT CRYST C, 56, 2000, pp. E434-E434
Citations number
6
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
10
Pages
E434 - E434
Database
ISI
SICI code
0108-2701(200010)56:<E434:TDFOAP>2.0.ZU;2-W
Abstract
The title paramagnetic compound, chloro-2 kappa Cl-[di-tert-butylphosphinic ethylamide-1 kappaO]bis[mu -di-tert-butylphosphinic ethylamidato(1-)-1:2 k appa O-4:N]lithium(I)nickel(II), [NiLiCl-(C-10 H23NOP)(2)(C10H24NOP)], reve aled an incomplete bischelation of Ni2+ by L- {L = [(Bu2P)-Bu-t(O)NEt](-)}, with the formation of a pseudo-tetrahedral NiON2Cl chromophore. The Ni ato m is coordinated by Cl-, bidentate L- and monodentate LLi (via N).