cis-Dibromo-trans-dimethyl-cis-bis(N,N-dimethylacetamide)tin(IV)

Citation
Uc. Konig et al., cis-Dibromo-trans-dimethyl-cis-bis(N,N-dimethylacetamide)tin(IV), ACT CRYST C, 56, 2000, pp. E452-E453
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
10
Pages
E452 - E453
Database
ISI
SICI code
0108-2701(200010)56:<E452:C>2.0.ZU;2-Y
Abstract
The synthesis and X-ray structure analysis of the title compound, [SnBr2(CH 3)(2)(C4H9NO)(2)], are described. The crystal contains molecules which are separated by normal van der Waals distances. Organotin(IV) compounds are fo und in a variety of structural types, in which the Sn atom can, for example , be hexacoordinated. In this case, the preferred solid-state molecular str ucture of the central atom is octahedral. The degree of distortion and the configuration depend on the ligands.