Dichlorobis(1,2-phenylenediamine)-nickel(II)

Authors
Maxcy, KR Smith, R Willett, RD Vij, A
Citation
Kr. Maxcy et al., Dichlorobis(1,2-phenylenediamine)-nickel(II), ACT CRYST C, 56, 2000, pp. E454-E454
Citations number
3
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
10
Pages
E454 - E454
Database
ISI
SICI code
0108-2701(200010)56:<E454:D>2.0.ZU;2-P
Abstract
The title compound, [NiCl2(C6H8N2)(2)], contains centrosymmetric molecules with two phenylenediamine ligands coordinated in a bidentate fashion. The N i-N distances are 2.088 (1) and 2.096 (1) Angstrom, and the Ni-Cl distance of 2.4635 (4) Angstrom. The plane of each phenylenediamine molecule makes a dihedral angle of 26.53 (7)degrees with the NiN4 plane. Extensive hydrogen bonding leads to distinct cleavage in the bc plane.