2,4,5-Triphenyl-4H-imidazol-4-yl hydroperoxide-dichloromethane (2/1)

Authors
Hu, ZZ Takami, S Kimura, M Tachi, Y Naruta, Y
Citation
Zz. Hu et al., 2,4,5-Triphenyl-4H-imidazol-4-yl hydroperoxide-dichloromethane (2/1), ACT CRYST C, 56, 2000, pp. E465-E466
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
10
Pages
E465 - E466
Database
ISI
SICI code
0108-2701(200010)56:<E465:2H(>2.0.ZU;2-3
Abstract
The structure of lophine peroxide was confirmed to be 2,4,5-triphenyl-4H-im idazol-4-yl hydroperoxide and not the 2,5-endoperoxide. The asymmetric unit is composed of an O-H . . . N hydrogen-bonded dimer of lophine peroxide wi th an R/ R or S/S configuration and a CH2Cl2 solvent molecule, i.e. 2C(21)H (16)N(2)O(2). CH2Cl2.