Benzyl 5-carboxy-4-ethyl-3-methylpyrrole-2-carboxylate

Citation
Mr. Silva et al., Benzyl 5-carboxy-4-ethyl-3-methylpyrrole-2-carboxylate, ACT CRYST C, 56, 2000, pp. 1263-1264
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
10
Pages
1263 - 1264
Database
ISI
SICI code
0108-2701(200010)56:<1263:B5>2.0.ZU;2-K
Abstract
In the title compound, C16H17NO4, the benzyloxycarbonyl group is anti to th e pyrrolic N atom. The molecules are joined into head-to-head dimers by hyd rogen bonds involving the carboxylic acid groups. There is orientational di sorder of these groups over two positions with approximately equal occupanc y. A weaker hydrogen bond between the pyrrolic N atom and the carbonyl O at om of the benzyloxycarbonyl group joins the dimers into chains running para llel to the [110] direction.