(5S)-3-Oxo-4-oxa-endo-tricyclo-[5.2.1.0(2,6)]dec-8-en-5-yl acetate

Citation
Dd. Ellis et Al. Spek, (5S)-3-Oxo-4-oxa-endo-tricyclo-[5.2.1.0(2,6)]dec-8-en-5-yl acetate, ACT CRYST C, 56, 2000, pp. 1269-1270
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
10
Pages
1269 - 1270
Database
ISI
SICI code
0108-2701(200010)56:<1269:(A>2.0.ZU;2-B
Abstract
The molecular structure of C11H12O4, based on a norbornene core, was establ ished to confirm the configuration of an acetoxy side-chain group in additi on to the formation of the endo product. The acetoxy side chain lies in an axial position relative to the five-membered fused ring. Bond distances and angles show no unusual features, with all geometric parameters lying withi n their expected ranges. The overall stereochemistry of the molecule was as certained from the chiral furanone starting material.