A sensitive novel approach of using an amperometric ion detector for the no
w injection analysis of salts has been developed. The detection methodology
is based on measuring the-current associated with the transfer of ions acr
oss polarized microinterfaces between the aqueous sample solution and a 2-n
itrophenyloctyl ether-poly(vinyl chloride) gel phase, referred to as ionode
s, Different sodium salts of fluoride, chloride, bromide, nitrate, and sulf
ate were investigated. It was found that by employing an amperometric pulse
detection mode and pure water as eluent; the detection limit of the ionode
detector could be lowered to ppt level of salt concentrations under flowin
g conditions.