An electrospray ionization source for the investigation of thermally initiated reactions

Authors
Griep-Raming, J Metzger, JO
Citation
J. Griep-raming et Jo. Metzger, An electrospray ionization source for the investigation of thermally initiated reactions, ANALYT CHEM, 72(22), 2000, pp. 5665-5668
Citations number
22
Categorie Soggetti
Chemistry & Analysis","Spectroscopy /Instrumentation/Analytical Sciences
Journal title
ANALYTICAL CHEMISTRY
ISSN journal
00032700 → ACNP
Volume
72
Issue
22
Year of publication
2000
Pages
5665 - 5668
Database
ISI
SICI code
0003-2700(20001115)72:22<5665:AEISFT>2.0.ZU;2-L
Abstract
An electrospray ionization source for mass spectrometry is described, which allows one to heat the spray capillary. Thermal dissociation of the trityl dimer 1 and tetra(p-anisyl)hydrazine (3) have been investigated, operating the ESI source as electrolytic cell to ionize neutral species, e.g. the tr ityl radical 2.