In-line bulk concentration measurement by method of conductivity in industrial KDP crystal growth from aqueous solution

Citation
Sl. Wang et al., In-line bulk concentration measurement by method of conductivity in industrial KDP crystal growth from aqueous solution, CRYST RES T, 35(9), 2000, pp. 1027-1034
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CRYSTAL RESEARCH AND TECHNOLOGY
ISSN journal
02321300 → ACNP
Volume
35
Issue
9
Year of publication
2000
Pages
1027 - 1034
Database
ISI
SICI code
0232-1300(2000)35:9<1027:IBCMBM>2.0.ZU;2-Q
Abstract
The conductivity of KH2PO4 (KDP) aqueous solutions with varying saturation temperature from 28.5 degreesC to 41.8 degreesC was measured in the tempera ture range of 30 degreesC to 40 degreesC. It's proposed that the conductivi ty of KDP solutions can be expressed by L=L-0+b(1)T+b(2)T(2). This relation can be interpreted by Falkenhagen's (1971) conductivity model of high conc entration electrolyte solution. The experimental data agrees well to the re lation with an accuracy of super-saturation within +/-0.03g KDP/100g water (+/-0.10% relative super-saturation).