Arylation of palladium(II) and platinum(II) by diphenyliodonium triflate to form metal(IV) species, and a structural analysis of an isomer of PtIMe2Ph(bpy) (bpy=2,2 '-bipyridine)

Authors
Bayler, A Canty, AJ Ryan, JH Skelton, BW White, AH
Citation
A. Bayler et al., Arylation of palladium(II) and platinum(II) by diphenyliodonium triflate to form metal(IV) species, and a structural analysis of an isomer of PtIMe2Ph(bpy) (bpy=2,2 '-bipyridine), INORG CH C, 3(11), 2000, pp. 575-578
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
11
Year of publication
2000
Pages
575 - 578
Database
ISI
SICI code
1387-7003(200011)3:11<575:AOPAPB>2.0.ZU;2-E
Abstract
The first example of aryl transfer to palladium(II) with concomitant oxidat ion to palladium(IV) is reported, utilising the reaction of PdMe2(bpy) (bpy = 2,2'-bipyridine) with [IPh2][O3SCF3], together with studies of an analog ous platinum system and a structural analysis of trans-PtIMe2Ph(bpy) (bpy = 2,2'-bipyridine). (C) 2000 Elsevier Science S.A. All rights reserved.