Photoluminescence of tetrameric platinum(II) acetate in solution

Authors
Kunkely, H Vogler, A
Citation
H. Kunkely et A. Vogler, Photoluminescence of tetrameric platinum(II) acetate in solution, INORG CH C, 3(11), 2000, pp. 594-596
Citations number
16
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
11
Year of publication
2000
Pages
594 - 596
Database
ISI
SICI code
1387-7003(200011)3:11<594:POTPAI>2.0.ZU;2-D
Abstract
Tetrameric Pt(II) acetate shows a photoluminescence in solution at lambda ( max) = 510 nm and 630 nm which is assigned to a metal-centered fluorescence (tau < 5 ns) and phosphorescence ( <tau> = 1.8 ys), respectively. It is su ggested that in the emissive excited state the metal-metal bonds are weaken ed. (C) 2000 Elsevier Science S.A. All rights reserved.