Polyoxometalate coordinated phosphato complexes: a possible model reactionfor POM-nucleotide interaction

Authors
Peng, J Li, WZ Wang, EB Zhao, XL Huang, BQ
Citation
J. Peng et al., Polyoxometalate coordinated phosphato complexes: a possible model reactionfor POM-nucleotide interaction, INORG CH C, 3(11), 2000, pp. 615-616
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
11
Year of publication
2000
Pages
615 - 616
Database
ISI
SICI code
1387-7003(200011)3:11<615:PCPCAP>2.0.ZU;2-J
Abstract
The dephosphorylation of ATP in the presence of unsaturated heteropoly anio n [SiW11O39](8-) and transition metal ions, Mn-II, Co-II, Ni-II and Zn-II g enerates phosphato derivatives, formulated as [SiW11O39M(P2O7)](10-), (M = Mn-II, Co-II, Ni-II and Zn-II), which were also synthesized from pyrophosph ate as a possible model reaction of polyoxometalate-nucleotide interaction. (C) 2000 Published by Elsevier Science S.A.