Oxidation of organic substrates catalyzed by a novel mixed-ligand [Ru-III(app) (pic) (H2O)](+) complex

Authors
Chatterjee, D Mitra, A
Citation
D. Chatterjee et A. Mitra, Oxidation of organic substrates catalyzed by a novel mixed-ligand [Ru-III(app) (pic) (H2O)](+) complex, INORG CH C, 3(11), 2000, pp. 640-644
Citations number
25
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
11
Year of publication
2000
Pages
640 - 644
Database
ISI
SICI code
1387-7003(200011)3:11<640:OOOSCB>2.0.ZU;2-A
Abstract
Cationic [Ru-III(app)(pic)(H2O)](+) (1) complex (Happ = N-(hydroxyphenyl)py ridine-2-carboxaldimine; Hpic = picolinic acid) has been synthesized and ch aracterized by physico-chemical methods and employed as catalyst in the oxi dation of both saturated and unsaturated hydrocarbons using tert-butylhydro peroxide (t-BuOOH). A mechanism involving formation of and transfer from a reactive high valent Ru(V)-oxo species as catalytic intermediate is propose d for the catalytic processes. (C) 2000 Elsevier Science B.V. All rights re served.