An accurate determination of cloud particle phase is required for the retri
eval of other cloud properties from satellite and for radiative flux calcul
ations in climate models. The physical principles underlying phase determin
ation using the advanced very high resolution radiometer (AVHRR) satellite
sensor are described for daytime and nighttime, cold cloud and warm cloud c
onditions. It is demonstrated that the spectral properties of cloud particl
es provide necessary, but not sufficient, information for phase determinati
on, because the relationship between the cloud and surface temperatures is
also important. Algorithms based on these principles are presented and test
ed. Validation with lidar and aircraft data from two Arctic held experiment
s shows the procedures to be accurate in identifying the phase of homogeneo
us water and ice clouds, though optically thin, mixed-phase, and multilayer
clouds are problematic.